Detailed mineragraphy and electron probe analysis were carried out on the samples from Hongling, Shirenzhang, Meiziwo and Jubankeng vein type tungsten deposits in northern Guangdong Province, China. The authors found several grains of mangancolumbite and wolframoixiolite and observed a wide range of intergrowth phenomenon of wolframite and scheelite in the Hongling deposit. Some stannites even include cassiterite.Silver mineralization to some extent occurs in the Hongling, shirenzhang and Meiziwo tungsten deposits. Based on the EDX analysis of Ag-bearing minerals, Ag-bearing heyrovskyite, schirmerite (No.1, 2, 3 subspecies), matildite, proustite, stephanite, a stromeyerite have been identified with minor unnamed Pb-Bi-S minerals (4.78%~13.25% Ag), Ag-Cu-S minerals (2.9%~12.19% Ag), As-S-Ag minerals (71.01%~90.74% Ag), and Cl-Pb-Cu-S mineral (9.3% Ag). Silver-bearing minerals in the Hongling deposit are mainly scattered as irregular grains in sphalerite and silicate minerals, and formed simultaneously as the main sulfides did.