New total organic carbon (TOC) data from the two Ordovician–Silurian transitional graptolite-bearing black shale intervals, the Wufeng Formation and the Longmaxi Formation in Central Guizhou and West Hubei, respectively, as well as previously reported TOC data from the same intervals in other places on the Yangtze platform of South China, have been used to produce an initial estimate of the primary paleoproductivity via a conventional inverse method (i.e., Rpp-inverse). The values of the Rpp-inverse are estimated to be 32 (43–21) gC/(m2·a) (Wufeng Formation) and 21 (27–16) gC/(m2·a) (Longmaxi Formation). The difference in the results via the two methods suggests that paleoproductivity estimates from the geological strata need to be made cautiously, with particular attention paid to the paleogeographic setting, oxic-anoxic conditions, as also the preservation factor of organic carbon.