An analytical method which could simultaneously determine Sb, As, Cu, Pb and Zn in antimony ores by Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) with a multi-directional observation mode is reported in this paper. The results show that the method has higher sensitivity and a lower detection limit. The method is simple, rapid and accurate to meet the analytical requirement for determination of the Sb, As, Cu, Pb and Zn in antimony ore samples.