The Shapinggou porphyry molybdenum deposit located in the western margin of the Dabie Mountains is the newly-discovered largest Mo deposit in China. It is part of the east extension of the Qinling-Dabie Mo mineralization belt. The main orebody is concealed with weak Mo mineralization. Mo deposits mainly occur in high-K granitic porphyry and quartz syenite. Field observation and drilling data reveal that Mo mineralization is closely related to collaspe of breccia. The geochemical data indicate granitic porphyry is characterized by acid, sub-alkaline, high K2O, low Na2O and Ca2O. Re-Os dating of molybdenite for the porphyry deposit yields an isochron age of (111.1±1.2) Ma.