The REE distribution patterns of iron-rich siliceous rock samples in Bikou terrane showed commonly with Eu positive anomalies,δEu=1.02~8.79, varied Ce negative anomalies,δCe=0.44~1.26, and relative depleted LREE and enriched HREE, (La/Yb)N=0.071~1.285. These parameters are similar to those of hydrothermal vent fluid on modern seafloor and indicate that the siliceous rocks were hydrothermal exhalative sedimentation generated by the convectional mixing of seawater and hydrothermal fluid on ancient seafloor. Y/Ho ratio in siliceous rock samples ranges from 22 to 47, correlating with Ce/Ce* ratios obviously, reflecting that both ratios were controlled by two end members of hydrothermal fluid and seawater.