安徽黄山花岗岩岩石学、矿物学及地球化学研究
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摘要
安徽黄山复式岩体位于扬子板块东南缘,江南陆内造山带内。黄山复式岩体由太平花岗闪长岩岩体和黄山花岗岩岩体组成。根据岩体的接触关系和各期次岩石的矿物学及岩石学特征,可以将黄山花岗岩岩体分为4个期次:第一期为中粒二长花岗岩;第二期为粗粒似斑状花岗岩;第三期为中细粒斑状花岗岩;第四期为粗粒含斑花岗岩。从矿物的组成上来看,各期次的岩石均为广义的花岗岩类,主要矿物以石英和长石为主,太平岩体和黄山岩体中的斜长石均表现出钠长石的特点,同时黄山岩体特征的出现条纹长石。各期次岩体均含有少量的铁白云母,显示出过铝质的特点。各期次岩石总体具有高硅(SiO_2含量大于75%)、高碱(ALK含量大于7.9%)、低钙(CaO含量小于1%)及高FeO~T/MgO比值(13~37)的特点。同时岩石强烈富集稀土元素(除Eu出现明显的负异常)、Zr、Hf、Nb等高场强元素,贫Ba、Sr、Ni,高10000×Ga//Al(比值大于2.6),这些特征均指示黄山复式岩体具有A型花岗岩的特点。通过Eby的判别图解将其进一步划分为A2型花岗岩,代表其形成于拉张的构造背景之下。结合Sm-Nd同位素特征(ε_(Nd)(t)=-4.2~-5.6),确定黄山复式岩体的源区物质可能为一套元古宙的火山岩。同时稀土模拟结果表明,黄山岩体的原始岩浆是这种源区大约20%部分熔融的产物。岩体形成于斜向俯冲引发的陆内剪张环境内。
The Huangshan granite intrusion situated in Anhui Province,southeast of China,is located at the southeastern boundary of Yangtze plate.The Huangshan granite intrusion consists of Taiping granodiorite and Huangshan granite.Based on the contact relationship,the Huangshan granite can be divided into four stages(from early to late):medium-grained monzogranite,coarse-grained porphyric granite,fine-medium grained porphyric granite,fine-coarse grained granite.All stages of the granitoids have similar mineralogical components which are composed of Fe-muscovite,K-feldspar,albite and quartz.The presence of Fe-muscovite indicates that the Huangshan granite intrusion is peraluminous.The granitoids are characterized by high SiO_2(>75%),alkali(7.9%~8.6%),low CaO(<1%) and high FeO~T/MgO(13~37).The granitoids also have relatively high REE content(except for Eu), high strength field elements such as Zr、Hf、Nb,low Ba、Sr、Ni,and high 10000×Ga/Al(>2.6),indicating A-type granitoids.On the base of the classification diagrams proposed by Eby,the Huangshan granitoids can be classified into A2,which is usually believed to be formed under an extensional tectonic setting.Their Nd isotopic compositions suggest that the primary magmas of the Huangshan intrusion are derived from the Proterozoic andesitic rocks in the region,and the REE model also supports the conclusion.The late Mesozoic Huangshan intrusion can provide some important petrologic constrains on the transitional tectonic in southeastern China.
The Huangshan granite intrusion situated in Anhui Province,southeast of China,is located at the southeastern boundary of Yangtze plate.The Huangshan granite intrusion consists of Taiping granodiorite and Huangshan granite.Based on the contact relationship,the Huangshan granite can be divided into four stages(from early to late):medium-grained monzogranite,coarse-grained porphyric granite,fine-medium grained porphyric granite,fine-coarse grained granite.All stages of the granitoids have similar mineralogical components which are composed of Fe-muscovite,K-feldspar,albite and quartz.The presence of Fe-muscovite indicates that the Huangshan granite intrusion is peraluminous.The granitoids are characterized by high SiO_2(>75%),alkali(7.9%~8.6%),low CaO(<1%) and high FeO~T/MgO(13~37).The granitoids also have relatively high REE content(except for Eu), high strength field elements such as Zr、Hf、Nb,low Ba、Sr、Ni,and high 10000×Ga/Al(>2.6),indicating A-type granitoids.On the base of the classification diagrams proposed by Eby,the Huangshan granitoids can be classified into A2,which is usually believed to be formed under an extensional tectonic setting.Their Nd isotopic compositions suggest that the primary magmas of the Huangshan intrusion are derived from the Proterozoic andesitic rocks in the region,and the REE model also supports the conclusion.The late Mesozoic Huangshan intrusion can provide some important petrologic constrains on the transitional tectonic in southeastern China.
引文
[1]黄山管委会.2003.黄山世界地质公园申请书.下文中涉及到的黄山管委会的内容均引自此申请书
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Foster MD.1960.Interpretation of the composition of trioctahedral micas. U.S.Geol.Suvey,Prof.Paper,354
Fujimaki H,Tatsumoto M and Aoki K.1984.Partition coefficients of Hf, Zr and REE between phenocrysts and groundmass.In:Proc.14th Lunar and Planetary Science Conf.,part 2.J.Geophys.Res.,89 (Suppl.):B662-B672
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Irving AJ and Frey FA.1978.Distribution of trace elements between garnet megacrysts and host volcanic liquids of kimberlitic to rhyolitic composition.Geochim.Cosmochim.Acta,42:771-787
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Morrison GW.1980.Characteristics and tectonic setting of the shoshonite rock association.Lithos,13(1):97-108
Nash WP and Crecraft HR.1985.Partition coefficients for trace elements in silicic magmas.Geochim.Cosmochim.Acta,49:2309-2322
Pearce JA,Harris NBW and Tindle AG.1984.Trace element discrimination diagrams for the tectonic interpretation of granitic rocks.J.Petrol.,25:956-983
Qiu RL.1998.Magmatic differention and genesis of Jiuhuashan granite. Acta Petrologica et Mineralogica,17(4):308-315(in Chinese with English abstract)
Rickwood PC.1989.Boundary lines within petrologic diagrams which use oxides of minor elements.Lithos,22:247-263
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Sun SS and McDoungh.1989.Chemical and isotopic systematics of oceanic basalts:Implications for mantle composition and processes. In:Saunders AD and Norry MJ(eds.).Magmatism in the Ocean Basins.Geological Society,42:313-345
Shen WZ,Ling HF,Li WX,Huang XL and Wang DZ.1999.Study on the Nd-Sr Isotopic Compositions of Granitoids in SE China. Geological Journal of China Universities,5(1):22-32(in Chinese with English abstract)
Su YP and Tang HF.2005.Trace element geochemistry of A-type granites.Bulletin of Mineralogy,Petrotogy and Geochemistry,24 (3):245-250(in Chinese with English abstract)
Sun N,Liu CS and Zhao ZL.1982.Magmatic differentiation and genesis of the Huangshan-Taiping intrusion complex.In:Geology of Granites and Their Metallogenetic Relation.Beijing:Science Press(in Chinese with English abstract)
Watson EB.1979.Zircon saturation in felsic liquids:Experimental data and applications to trace element geochemistry.Contrib.Mineral. Petrol.,95:407-419
Whalen JB.1987.A-type granites:Geochemical characteristics, discrimination and petrogenesis.Contributions to Mineralogy and Petrology,95:407-419
Wang DZ,Zhao GT and Qiu JS.1995.The tectonic constraint on the Late Mesozoic A-type granitoids in eastern China.Geological Journal of China Universities,1(2):13-21(in Chinese with English abstract)
Wu FY,Li XH,Yang JH and Zheng YF.2007.Discussions on the petrogenesis of unites.Acta Petrologica Sinica,23(6):1217 - 1238 (in Chinese with English abstract)
Wu RX,Zheng YF and Wu YB.2007.Zircon U-Pb Age and Isotope Geochemistry of Neoproterozoic Jingtan Volcanics in South Anhui. Geological Journal of China Universities,13(2):282-296(in Chinese with English abstract)
Wu SP,Wang MY and Qi KJ.2007.Present situation of researches on A type granites:A review.Acta Petrologica et Mineralogica,26(1): 57-66(in Chinese with English abstract)
Xing FM and Xu X.1994.Two A-type granitoids belts in Anhui.Acta Petrologica Sinica,10(4):357-369(in Chinese with English abstract)
Yu XQ,Jiang LL,Xu W,Qiu RL,Du JG and Dai SQ.2007. ??Identification and basic characteristics of the Anhui Zhejiang Jiangxi fault zone.Earth Science Frontiers,14(3):102-113(in Chinese with English abstract)
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Zhang ZC,Jian P and Wei HR.2007.SHRIMP ages,geology, geochemistry and petrogenetic type of granites from the Sanqingshan Geopark,Jiangxi Province.Geological Review,53(Supp.):28- 40(in Chinese with English abstract)
Zhou TX and Chen JF.1995.Nd isotope ratios of sedimentary rocks from the southeastern margin of Yangtze Block China.Acta Sedimentologica Sinica,13(3):39-45(in Chinese with English abstract)
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Bureau of Geology of Anhui Province.The Regional Geology of Anhui Province.Beijing:Geological Publishing House,723
Arth JG.1976.Behaviour of trace elements during magmatic processes: A summary of theoretical models and their applications.J.Res.US Geol.Surv.,4:41-47
Bao ZW and Zhao ZH.2003.Geochemistry and tectonic setting of the Fugang aluminous A-type granite,Guangdong Province,China:A preliminary study.Geology-Geochemistry,31:52-60(in Chinese with English abstract)
Charoy B and Raimbault L.1994.Zr,Th and REE rich biotite differentiaties in the A-type granite pluton of Suzhou(Eastern China):The key role of flurine.J.Petrol,35:919-962
Chen HW,Luo ZH,Mo XX,Liu CD and Ke S.2005.Underplating mechanism of Triassic granite of magma mixing origin in the east Kunlun orogenic belt.Geology in China,32(3):386 -395
Cben JF,Foland KA and Liu YM.1993.Precise~(40)Ar-~(39) Ar dating of Suzhou composite granite.Acta Petrologica Sinica,9:77-85(in Chinese with English abstract)
Clemens JD,Holloway JR and White JAR.1986.Origin of an A-type granites:Experimental constrains.Am.Mineral,71:317-324
Eby GN.1992.Chemical subdivision of the A-type granitoids: Petrogenetic and tectonic implications.Geology,20:641-644
Eby GN.1990.The A-type granitoids:A review of their occurrence and chemical characteristics and speculations on their petrogenesis. Lithos,26:115-134
Foster MD.1960.Interpretation of the composition of trioctahedral micas. U.S.Geol.Suvey,Prof.Paper,354
Fujimaki H,Tatsumoto M and Aoki K.1984.Partition coefficients of Hf, Zr and REE between phenocrysts and groundmass.In:Proc.14th Lunar and Planetary Science Conf.,part 2.J.Geophys.Res.,89 (Suppl.):B662-B672
Fujimaki H.1986.Partition coefficients of Hf,Zr and REE between zircon,apatite and liquid.Contrib.Mineral.Petrol,94:42-45
Irving AJ and Frey FA.1978.Distribution of trace elements between garnet megacrysts and host volcanic liquids of kimberlitic to rhyolitic composition.Geochim.Cosmochim.Acta,42:771-787
Jiang YH,Qie JZ,Liu HY and Wang WG.1999.A2-type granite in neighbouring area of Zbejiang-Jiangxi-Anhui provinces.Volcanology and Mineral Rescourses,20(1):48-55(in Chinese with English abstract)
Li SY,Wang DX,Jin FQ and Yan HX.1996.Geochemical characteristics of Leigongwu Formation and its tectonics setting in southern Anhui.Geology of Anhui,4(6):15 -22(in Chinese with English abstract)
Liu CS,Chen XM,Chen PR,Wang RC and Hu H.2003a.Subdivision, discrimination criteria and genesis for A type rock suites.Geological Journal of China Universities,9(4):573-591(in Chinese with English abstract)
Liu CS,Chen XM,Wang RC and Hu H.2003b.Origin of Nankunshan aluminous A type granite,Longkou County,Guangdong Province. Acta Petrologica et Mineralogica,22(1):1-10(in Chinese with English abstract)
Maniar PD and Piccoli PM.1989.Tectonic discrimination of granitoids. Geological Society of America Bulletin,101:635-643
Morrison GW.1980.Characteristics and tectonic setting of the shoshonite rock association.Lithos,13(1):97-108
Nash WP and Crecraft HR.1985.Partition coefficients for trace elements in silicic magmas.Geochim.Cosmochim.Acta,49:2309-2322
Pearce JA,Harris NBW and Tindle AG.1984.Trace element discrimination diagrams for the tectonic interpretation of granitic rocks.J.Petrol.,25:956-983
Qiu RL.1998.Magmatic differention and genesis of Jiuhuashan granite. Acta Petrologica et Mineralogica,17(4):308-315(in Chinese with English abstract)
Rickwood PC.1989.Boundary lines within petrologic diagrams which use oxides of minor elements.Lithos,22:247-263
Rollinson H.1993.Using geochemical data:Evaluation,presentation, interpretation.Longman Scientific & Technical,Harlow,United Kingdom,352
Sun SS and McDoungh.1989.Chemical and isotopic systematics of oceanic basalts:Implications for mantle composition and processes. In:Saunders AD and Norry MJ(eds.).Magmatism in the Ocean Basins.Geological Society,42:313-345
Shen WZ,Ling HF,Li WX,Huang XL and Wang DZ.1999.Study on the Nd-Sr Isotopic Compositions of Granitoids in SE China. Geological Journal of China Universities,5(1):22-32(in Chinese with English abstract)
Su YP and Tang HF.2005.Trace element geochemistry of A-type granites.Bulletin of Mineralogy,Petrotogy and Geochemistry,24 (3):245-250(in Chinese with English abstract)
Sun N,Liu CS and Zhao ZL.1982.Magmatic differentiation and genesis of the Huangshan-Taiping intrusion complex.In:Geology of Granites and Their Metallogenetic Relation.Beijing:Science Press(in Chinese with English abstract)
Watson EB.1979.Zircon saturation in felsic liquids:Experimental data and applications to trace element geochemistry.Contrib.Mineral. Petrol.,95:407-419
Whalen JB.1987.A-type granites:Geochemical characteristics, discrimination and petrogenesis.Contributions to Mineralogy and Petrology,95:407-419
Wang DZ,Zhao GT and Qiu JS.1995.The tectonic constraint on the Late Mesozoic A-type granitoids in eastern China.Geological Journal of China Universities,1(2):13-21(in Chinese with English abstract)
Wu FY,Li XH,Yang JH and Zheng YF.2007.Discussions on the petrogenesis of unites.Acta Petrologica Sinica,23(6):1217 - 1238 (in Chinese with English abstract)
Wu RX,Zheng YF and Wu YB.2007.Zircon U-Pb Age and Isotope Geochemistry of Neoproterozoic Jingtan Volcanics in South Anhui. Geological Journal of China Universities,13(2):282-296(in Chinese with English abstract)
Wu SP,Wang MY and Qi KJ.2007.Present situation of researches on A type granites:A review.Acta Petrologica et Mineralogica,26(1): 57-66(in Chinese with English abstract)
Xing FM and Xu X.1994.Two A-type granitoids belts in Anhui.Acta Petrologica Sinica,10(4):357-369(in Chinese with English abstract)
Yu XQ,Jiang LL,Xu W,Qiu RL,Du JG and Dai SQ.2007. ??Identification and basic characteristics of the Anhui Zhejiang Jiangxi fault zone.Earth Science Frontiers,14(3):102-113(in Chinese with English abstract)
Zhang DQ and Xu HL.2007.Geological and geochemical contrastive study on the granitoids from Middle-Lower Reach of the Yangtze River.Geology and Mineral Resources of South China,(3):66- 77(in Chinese with English abstract)
Zhang H,Dai SQ,Guan YC and Wu HQ.2005.Petrolagy and geochemistry of the Fining mass in.Jixi,southern Anhui.Geology in China,32(3):411-416(in Chinese with English abstract)
Zhang ZC,Jian P and Wei HR.2007.SHRIMP ages,geology, geochemistry and petrogenetic type of granites from the Sanqingshan Geopark,Jiangxi Province.Geological Review,53(Supp.):28- 40(in Chinese with English abstract)
Zhou TX and Chen JF.1995.Nd isotope ratios of sedimentary rocks from the southeastern margin of Yangtze Block China.Acta Sedimentologica Sinica,13(3):39-45(in Chinese with English abstract)
安徽地质矿产局.1987.安徽省区域地质志.北京:地质出版社,723
包志伟,赵振华.2003.佛冈铝制A型花岗岩的地球化学及其形成环境的初探.地质地球化学,31(1):52-60
陈江峰,Fdand KA,刘义茂.1993.苏州复式花岗岩体的精确~(40)Ar-~(39) Ar定年.岩石学报,9:77-85
谌宏伟,罗照华,莫宜学,刘成东,柯珊.2005.东昆仑造山带三叠纪岩浆混合成因花岗岩的岩浆底侵作用机制.中国地质,32(3): 386-395
姜耀辉,戚建中,刘红樱,王文岗.1999.浙赣皖相邻地区A2型花岗岩.火山地质与矿产,加(1):48-55
李双应,王道轩,颜怀学,金福全.1996.皖南雷公坞组地球化学特征及其大地构造意义.安徽地质,6(4):15-22
刘昌实,陈小明,陈培荣,王汝成,胡欢.2003a.A型岩套的分类、判别标志和成因.高校地质学报,9(4):573-591
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