Geochronology and Genesis of the Tiegelongnan Porphyry Cu(Au) Deposit in Tibet: Evidence from U-Pb, Re-Os Dating and Hf, S, and H-O Isotopes
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The Tiegelongnan Cu (Au) deposit is the largest copper deposit newly discovered in the Bangong&ndash;Nujiang metallogenic belt. The deposit has a clear alteration zoning consisting of, from core to margin, potassic to propylitic, superimposed by phyllic and advanced argillic alteration. The shallow part of the deposit consists of a high sulphidation-state overprint, mainly comprising disseminated pyrite and Cu&ndash;S minerals such as bornite, covellite, digenite, and enargite. At depth porphyry-type mineralization mainly comprises disseminated chalcopyrite, bornite, pyrite, and a minor vein molybdenite. Mineralization is disseminated and associated with veins contained within the porphyry intrusions and their surrounding rocks. The zircon U&ndash;Pb ages of the mineralized diorite porphyry and granodiorite porphyry are 123.1 &plusmn; 1.7 Ma (2&sigma;) and 121.5 &plusmn; 1.5 Ma (2&sigma;), respectively. The molybdenite Re&ndash;Os age is 121.2 &plusmn; 1.2 Ma, suggesting that mineralization was closely associated with magmatism. Andesite lava (zircon U&ndash;Pb age of 111.7 &plusmn; 1.6 Ma, 2&sigma;) overlies the ore-bodies and is the product of post-mineralization volcanic activity that played a critical role in preserving the ore-bodies. Values of &minus;4.6 ‰ to + 0.8 ‰ δ<sup>34sup>S for the metal sulfides (mean &minus; 1.55 ‰) suggest that S mainly has a deep magmatic source. The H and O isotopic composition is (δD = &minus;87 ‰ to &minus;64 ‰; δ<sup>18sup>O<sub>H2Osub> = 5.5 ‰ to 9.0 ‰), indicating that the ore-forming fluids are mostly magmatic-hydrothermal, possibly mixed with a small amount of meteoric water. The zircon &epsilon;<sub>Hfsub>(t) of the diorite porphyry is 3.7 to 8.3, and the granodiorite porphyry is 1.8 to 7.5. Molybdenite has a high Re from 382.2 &times; 10<sup>&minus;6sup> to 1600 &times; 10<sup>&minus;6sup>. Re and Hf isotope composition show that Tiegelongnan has some mantle source, maybe the juvenile lower crust from crust&ndash;mantle mixed source. Metallogenesis of the Tiegelongnan giant porphyry system was associated with intermediate to acidic magma in the Early Cretaceous (~120 Ma). The magma provenance of the Tiegelongnan deposit has some mantle-derived composition, possibly mixed with the crust-derived materials.

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