Metal-Free Autoxidative Nitrooxylation of Alkenyl Oximes with Molecular Oxygen

详细信息    查看全文

• 作者：Xiao-Wei Zhang ; Zu-Feng Xiao ; Yan-Jun Zhuang ; Mei-Mei Wang and Yan-Biao Kang
• 刊名：Advanced Synthesis & Catalysis
• 出版年：2016
• 出版时间：June 16, 2016
• 年：2016
• 卷：358
• 期：12
• 页码：1942-1945
• 全文大小：901K
• ISSN：1615-4169

文摘

A metal-free aerobic autoxidative nitrooxylation of alkenyl oximes mediated by tert-butyl nitrite is described. Molecular oxygen is used as the oxidizing reagent, avoiding use of organic trapping reagents such as 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO). The desired products were obtained in generally high yields.