NOUF6 Revisited: A Comprehensive Study of a Hexafluoridouranate(V) Salt

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• 作者：Benjamin Scheibe ; Sina Lippert ; Stefan S. Rudel ; Dr. Magnus R. Buchner ; Dr. Olaf Burghaus ; Clemens Pietzonka ; Prof. Dr. Martin Koch ; Prof. Dr. Antti J. Karttunen and Prof. Dr. Florian Kraus
• 刊名：Chemistry - A European Journal
• 出版年：2016
• 出版时间：August 16, 2016
• 年：2016
• 卷：22
• 期：34
• 页码：12145-12153
• 全文大小：1884K
• ISSN：1521-3765

文摘

We have synthesized NOUF₆ by direct reaction of NO with UF₆ in anhydrous HF (aHF). Based on the unit cell volume and powder diffraction data, the compound was previously reported to be isotypic to O₂PtF₆, however, detailed structural data, such as the atom positions and all information that can be derived from those, were unavailable. We have therefore investigated the compound by using single-crystal and powder X-ray diffraction, IR, Raman, NMR, EPR, and photoluminescence spectroscopy, magnetic measurements, as well as chemical analysis, density determination, and quantum chemical calculations.