ChemInform Abstract: Two 1-D Krebs-Type Heteropolyoxotungstates Based on [X₂W₂₁O₇₂Na(OH)₂]^13- (X: Sb^III, Bi^III) Units.

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• 作者：Hailou Li ; Shenzhen Chang ; Xing Ma ; Jinglin Liu ; Jie Luo and Junwei Zhao
• 刊名：ChemInform
• 出版年：2016
• 出版时间：November, 2016
• 年：2016
• 卷：47
• 期：47
• 全文大小：20K
• ISSN：1522-2667

文摘

[Me₂NH₂]₂Na₁₁ [X₂W₂₁NaO₇₂(OH)₂] ·34H₂O (X: Sb^III (I), Bi^III (II)) are prepared by a one-pot self-assembly of aqueous solutions of Na₂WO₄, NaOAc, and Me₂NH₂Cl to which a HCl solution of SbCl₃ (or Bi(NO₃)₃ and Zr(NO₃)₄ for (II)) is added dropwise.