Effective Polysulfide Rejection by Dipole-Aligned BaTiO<sub>3sub> Coated Separator in Lithium-Sulfur Batteries

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• 作者：Taeeun Yim ; Seung Ho Han ; Nam Hwan Park ; Min-Sik Park ; Ji Hoon Lee ; Jaeho Shin ; Jang Wook Choi ; Yongju Jung ; Yong Nam Jo ; Ji-Sang Yu and Ki Jae Kim
• 刊名：Advanced Functional Materials
• 出版年：2016
• 出版时间：November 15, 2016
• 年：2016
• 卷：26
• 期：43
• 页码：7817-7823
• 全文大小：2176K
• ISSN：1616-3028

文摘

Although the exceptional theoretical specific capacity (1672 mAh g<sup>−1sup>) of elemental sulfur makes lithium–sulfur (Li–S) batteries attractive for upcoming rechargeable battery applications (e.g., electrical vehicles, drones, unmanned aerial vehicles, etc.), insufficient cycle lives of Li–S cells leave a substantial gap before their wide penetration into commercial markets. Among the key features that affect the cyclability, the shuttling process involving polysulfides (PS) dissolution is most fatal. In an effort to suppress this chronic PS shuttling, herein, a separator coated with poled BaTiO<sub>3sub> or BTO particles is introduced. Permanent dipoles that are formed in the BTO particles upon the application of an electric field can effectively reject PS from passing through the separator via electrostatic repulsion, resulting in significantly improved cyclability, even when a simple mixture of elemental sulfur and conductive carbon is used as a sulfur cathode. The coating of BTO particles also considerably suppresses thermal shrinkage of the poly(ethylene) separator at high temperatures and thus enhances the safety of the cell adopting the given separator. The incorporation of poled particles can be universally applied to a wide range of rechargeable batteries (i.e., metal-air batteries) that suffer from cross-contamination of charged species between both electrodes.