ChemInform Abstract: Efficient Synthesis of Ir-Polyoxometalate Cluster Using a Continuous Flow Apparatus and STM Investigation of Its Coassembly Behavior on HOPG Surface.
Black needle-like crystals of K12Na2H2 [IrCl8P2W20O72] ·37H2O are prepared in a continuous-flow reactor from aqueous solutions of IrCl3, Na8[HPW9O34], NaH2PO4, Na2HPO4, KCl, and HCl (60 °C, 13% yield).