Bioinspired Nanocomposites: Ordered 2D Materials Within a 3D Lattice

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• 作者：Matteo Di Giosia ; Iryna Polishchuk ; Eva Weber ; Simona Fermani ; Luca Pasquini ; Nicola M. Pugno ; Francesco Zerbetto ; Marco Montalti ; Matteo Calvaresi ; Giuseppe Falini and Boaz Pokroy
• 刊名：Advanced Functional Materials
• 出版年：2016
• 出版时间：August 9, 2016
• 年：2016
• 卷：26
• 期：30
• 页码：5569-5575
• 全文大小：900K
• ISSN：1616-3028

文摘

Composites, materials composed of two or more materials—metallic, organic, or inorganic—usually exhibit the combined physical properties of their component materials. The result is a material that is superior to conventional monolithic materials. Advanced composites are used in a variety of industrial applications and therefore attract much scientific interest. Here the formation of novel carbon-based nanocomposites is described via incorporation of graphene oxide (GO) into the crystal lattice of single crystals of calcite. Incorporation of a 2D organic material into single-crystal lattices has never before been reported. To characterize the resulting nanocomposites, high-resolution synchrotron powder X-ray diffraction, electron microscopy, transmission electron microscopy, fluorescence microscopy and nanoindentation tests are employed. A detailed analysis reveals a layered distribution of GO sheets incorporated within the calcite host. Moreover, the optical and mechanical properties of the calcite host are altered when a carbon-based nanomaterial is introduced into its lattice. Compared to pure calcite, the composite GO/calcite crystals exhibits lower elastic modulus and higher hardness. The results of this study show that the incorporation of a 2D material within a 3D crystal lattice is not only feasible but also can lead to the formation of hybrid crystals exhibiting new properties.