The calculated Au<sub>38sub> cluster i
s repre
sented in the middle of the cover picture, coated by the N-heterocyclic carbene
s (NHC
s) pre
sented in the paper. The falling binary code “01” illu
strate
s that the Au<
sub>38
sub> clu
ster
s are i
ssued from DFT calculation
s. Molecular bi
s(NHC) gold complexe
s obtained from the functionalization of the particle
s are repre
sented around the clu
ster. An experimental <
sup>1
sup>H NMR
solid-
state
spectrum i
s shown in the lower part of the cover to remind the
reader that the
study combine
s experimental and computational approache
s. More information can be found in the Full Paper by F. Tielen
s, F. Remacle, S. Richeter et al. on
s:http://dx.doi.org/10.1002/chem.201601253">page 10446 ff.