The Reagent-depending Nitration of 1,3-Dihydroxyacetone Dimer
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- 作者：Tobias S. Hermann ; Thomas M. Klapö ; tke ; Burkhard Krumm and Jö ; rg Stierstorfer
- 刊名：Zeitschrift für anorganische und allgemeine Chemie
- 出版年：2017
- 出版时间：January 2017
- 年：2017
- 卷：643
- 期：2
- 页码：149-151
- 全文大小：288K
- ISSN：1521-3749
文摘
Two highly energetic nitric acid esters were synthesized from the dimer of dihydroxyacetone. 1,3-Dinitratoacetone (1) and its dimer 2,5-bis(nitratomethyl-2,5-nitrato)-1,4-dioxane (2) were characterized by single-crystal X-ray diffraction, vibrational spectroscopy (IR and Raman), multinuclear NMR spectroscopy, and elemental analysis. The thermal behavior was investigated with DTA measurements. Although showing the same atomic stoichiometry, dimer 2 shows significantly higher sensitivities measured by BAM methods (drophammer and friction tester). Due to the high oxygen content of 62.2 %, 1 and 2 were evaluated as potential high energy dense oxidizers.