Inside Back Cover: Redox-Active Tetraruthenium Macrocycles Built from 1,4-Divinylphenylene-Bridged Diruthenium Complexes (Chem. Eur. J. 28/2016)
详细信息 查看全文
- 作者：Stefan Scheerer ; Dr. Michael Linseis ; Dr. Evelyn Wuttke ; Sabrina Weickert ; Prof. Dr. Malte Drescher ; Dr. Oliver Trö ; ppner ; Prof. Dr. Ivana Ivanović-Burmazović ; Andreas Irmler ; Prof. Dr. Fabian Pauly and Prof. Dr. Rainer F. Winter
- 刊名：Chemistry - A European Journal
- 出版年：2016
- 出版时间：July 4, 2016
- 年：2016
- 卷：22
- 期：28
- 页码：9843
- 全文大小：3478K
- ISSN：1521-3765
文摘
Redox-active metallamacrocycles were built from 1,4-divinylphenylene-bridged diruthenium complexes and benzene-1,3-dicarboxylates. The nodal properties of the dicarboxylate ligands and the side-by-side placement of the phenylene linkers mutually insulate the conductive diruthenium building blocks. This has the interesting consequence of rendering the oxidized forms paramagnetic, while the polyelectrochromism of the individual building blocks is fully retained. More information can be found in the Full Paper by F. Pauly, R. F. Winter et al. on m.201601384" rel="references:http://dx.doi.org/10.1002/chem.201601384">page 9574 ff.