We examined a mixture of magnetite (Fe3O4) and iron (Fe) as a possible CO2 sorbent easily applicable for any ironmaking industries. The mixture reacts with CO2 to form siderite (FeCO3). Our experimental results illustrate a capture capacity of 7.98 mmolCO2g-1sorbent for the reactant mixture at 200 °C and 10 bar CO2 pressure in 3 h. The results also show that the kinetics of the carbonation reaction vastly depend on the applied temperature and CO2 pressure. The magnetite was completely regenerated by heating siderite at 350 °C under air flow. The proposed set of reactions can be integrated at any ironmaking sites and can provide a potential solution for CO2 capture in the future.