ChemInform Abstract: Mechanochemical Iridium(III)-Catalyzed C—H Bond Amidation of Benzamides with Sulfonyl Azides under Solvent-Free Conditions in a Ball Mill.
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- 作者：Gary N. Hermann ; Peter Becker and Carsten Bolm
- 关键词：sulfonamides (hydrazides ; ureides) (benzene compounds) ; amide formation ; microwave chemistry ; sonochemistry ; mechanochemistry ; green chemistry ; sustainable chemistry ; Editors' Choice
- 刊名：ChemInform
- 出版年：2016
- 出版时间：May, 2016
- 年：2016
- 卷：47
- 期：21
- 全文大小：26K
- ISSN：1522-2667
文摘
The mechanochemical activation enables the formation of an iridium species that catalyzes the ortho-selective amidation of benzamides with various sulfonyl azides in excellent yields within short times.