ChemInform Abstract: New Lanthanide Mixed-Valent Vanadium(III/IV) Oxosilicates, Ln4V5-xZnxSi4O22 (Ln: La, Ce, Pr, and Nd), Crystallizing in a Quasi Two-Dimensional Rutile-Based Structure.

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• 作者：Dileka Abeysinghe ; Mark D. Smith ; Jeongho Yeon ; Gregory Morrison and Hans-Conrad zur Loye
• 关键词：vanadium ; V ; lanthanoids ; structure (solids and liquids) ; zinc ; Zn ; silicon ; Si ; dielectric properties ; magnetic properties
• 刊名：ChemInform
• 出版年：2016
• 出版时间：April, 2016
• 年：2016
• 卷：47
• 期：18
• 全文大小：25K
• ISSN：1522-2667

文摘

Single crystals of the title compounds are grown via a molten flux method employing a 1:2:2 molar mixture of Ln₂O₃, V₂O₅, and Zn in a eutectic CsCl/NaCl mixture (evacuated silica tubes acting as Si source, 1000 °C, 24 h).