Donor-Stabilized 1,3-Disila-2,4-diazacyclobutadiene with a Nonbonded Si⋅⋅⋅Si Distance Compressed to a Si=Si Double Bond Length
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- 作者：Dr. David Gau ; Raphael Nougué ; Dr. Nathalie Saffon-Merceron ; Dr. Antoine Baceiredo ; Dr. Abel De Có ; zar ; Prof. Fernando P. Cossí ; o ; Dr. Daisuke Hashizume and Dr. Tsuyoshi Kato
- 刊名：Angewandte Chemie
- 出版年：2016
- 出版时间：November 14, 2016
- 年：2016
- 卷：128
- 期：47
- 页码：14893-14897
- 全文大小：1599K
- ISSN：1521-3757
文摘
A donor-stabilized 1,3-disila-2,4-diazacyclobutadiene presents an exceptionally short nonbonded Si⋅⋅⋅Si distance (2.23 Å), which is as short as that of Si=Si bonds (2.15–2.23 Å). Theoretical investigations indicate that there is no bond between the two silicon atoms, and that the unusual geometry can be related to a significant coulomb repulsion between the two ring nitrogen atoms. This chemical pressure phenomenon could provide an alternative and superior way of squeezing out van der Waals space in highly strained structures, as compared to the classical physical methods.