ChemInform Abstract: Reactions of Carbonyl Compounds with Phosphorus Ylide Generated from Tribromofluoromethane and Tris(dimethylamino)phosphine.

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• 作者：Go Hirai ; Eri Nishizawa ; Daiki Kakumoto ; Masaki Morita ; Mitsuaki Okada ; Daisuke Hashizume ; Sayoko Nagashima and Mikiko Sodeoka
• 关键词：olefination ; e/z-selectivity (incl. e/z-isomerism) ; halogen compounds (benzene compounds)
• 刊名：ChemInform
• 出版年：2016
• 出版时间：March, 2016
• 年：2016
• 卷：47
• 期：16
• 全文大小：31K
• ISSN：1522-2667

文摘

Reaction of the title ylide with simple aldehydes and ketones affords the expected Wittig products as mixtures of EIZ-isomers.