Structure and Isotope Effects of the β-H Agostic (α-Diimine)Nickel Cation as a Polymerization Intermediate

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• 作者：Dr. Hongwei Xu ; Dr. Paul B. White ; Dr. Chunhua Hu and Prof. Dr. Tianning Diao
• 刊名：Angewandte Chemie
• 出版年：2017
• 出版时间：February 1, 2017
• 年：2017
• 卷：129
• 期：6
• 页码：1557-1560
• 全文大小：848K
• ISSN：1521-3757

文摘

Single-crystal X-ray characterization of cationic (α-diimine)Ni-ethyl and isopropyl β-agostic complexes, which are key intermediates in olefin polymerization and oligomerization, are presented. The sharp Ni-C_α-C_β angles (75.0(3)° and 74.57(18)°) and short C_α−C_β distances (1.468(7) and 1.487(5) Å) provide unambiguous evidence for a β-agostic interaction. An inverse equilibrium isotope effect (EIE) for ligand coordination upon cleavage of the agostic bond highlights the weaker bond strength of Ni−H relative to the C−H bond. An Eyring plot for β-hydride elimination–olefin rotation–reinsertion is constructed from variable-temperature NMR spectra with ¹³C-labeled agostic complexes. The enthalpy of activation (ΔH^≠) for β-H elimination is 13.2 kcal mol⁻¹. These results offer important mechanistic insight into two critical steps in polymerization: ligand association upon cleavage of the β-agostic bonds and chain-migration via β-H elimination.