ChemInform Abstract: A Novel Copper-Rich Open-Framework Chalcogenide Constructed from Octahedral Cu4Se6 and Icosahedral Cu8Se13 Nanoclusters.
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文摘
The Cu-rich open-framework chalcogenide (pipH)10 [Cu16Sn6Se19(Se2)6] (pip: piperidine) is prepared by solvothermal reaction of the elements and piperidine (Cu:Sn:Se = 1.8:4.3:25, autoclave, 180 °C, 12 d; 19% yield).

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