Conformational Preferences and the Phase Stability of Fullerene Hexa-adducts

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• 作者：San-Lien Wu ; Chen-Yang Hong ; Kuan-Yi Wu ; Shih-Ting Lan ; Chou-Ting Hsieh ; Prof. Hsin-Lung Chen and Prof. Chien-Lung Wang
• 刊名：Chemistry – An Asian Journal
• 出版年：2016
• 出版时间：July 20, 2016
• 年：2016
• 卷：11
• 期：14
• 页码：2011-2015
• 全文大小：1478K
• ISSN：1861-471X

文摘

Molecular conformation and the assembly structure determine the spatial arrangements of the constituent units and the functions of a molecule. Although, fullerene hexa-adducts (FHAs) have been known as functional materials with great versatility, their conformational preferences and phase stability remain a complicate issue. By choosing bithiophene (T₂) and dodecyl bithiophene (C₁₂T₂) as the peripheral units of FHA, and using microscopic, scattering and diffraction characterizations, our study reveals how the intramolecular interaction and environmental stimulus affects the conformational preferences and phase stability of FHAs.