Fabrication of Chiral-Selective Nanotubular Heterojunctions through Living Supramolecular Polymerization

详细信息    查看全文

• 作者：Xiaojie Ma ; Yibin Zhang ; Yifan Zhang ; Yin Liu ; Prof. Dr. Yanke Che and Prof. Dr. Jincai Zhao
• 刊名：Angewandte Chemie International Edition
• 出版年：2016
• 出版时间：August 8, 2016
• 年：2016
• 卷：55
• 期：33
• 页码：9539-9543
• 全文大小：3862K
• ISSN：1521-3773

文摘

Novel, chiral-selective linear nanotubular heterojunctions were achieved by living supramolecular polymerization of perylenediimide (PDI) derivatives. We demonstrate that the chiral seed can effectively bias achiral PDI molecules to polymerize on its ends in the identical helical sense. More interestingly, the chiral seed can bias the opposite enantiomers to grow expitaxially from its ends even in excess amounts relative to the seed. Furthermore, we demonstrate that the biasing effect of the chiral seed on the opposite enantiomer is not dependent on the length of the chiral seed but is related to the intrinsic length of the elongated nanotube from the opposite enantiomer. The fabrication of chiral-selective nanotubes was achieved by application of the unique biasing effect of the chiral seed in living supramolecular self-assembly.