ChemInform Abstract: Selective Double Carbomagnesiation of Internal Alkynes Catalyzed by Iron-N-Heterocyclic Carbene Complexes: A Convenient Method to Highly Substituted 1,3-Dienyl Magnesium Reagents.
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- 作者：Yuesheng Liu ; Lijun Wang and Liang Deng
- 刊名：ChemInform
- 出版年：2016
- 出版时间：June, 2016
- 年：2016
- 卷：47
- 期：29
- 全文大小：29K
- ISSN：1522-2667
文摘
An iron(II)-N-heterocyclic carbene (NHC) complex is found to be effective as precatalyst for double carbometalation of unsymmetrical internal alkynes with Grignard-reagents.