Insights into the Reaction Mechanism of Ethanol Conversion into Hydrocarbons on H-ZSM-5
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- 作者：Kristof Van der Borght ; Rakesh Batchu ; Dr. Vladimir V. Galvita ; Dr. Konstantinos Alexopoulos ; Prof. Marie-Franç ; oise Reyniers ; Prof. Joris W. Thybaut and Prof. Guy B. Marin
- 刊名：Angewandte Chemie International Edition
- 出版年：2016
- 出版时间：October 4, 2016
- 年：2016
- 卷：55
- 期：41
- 页码：12817-12821
- 全文大小：2824K
- ISSN：1521-3773
文摘
Ethanol dehydration to ethene is mechanistically decoupled from the production of higher hydrocarbons due to complete surface coverage by adsorbed ethanol and diethyl ether (DEE). The production of Cb>3+ b> hydrocarbons was found to be unaffected by water present in the reaction mixture. Three routes for the production of Cb>3+ b> hydrocarbons are identified: the dimerization of ethene to butene and two routes involving two different types of surface species categorized as aliphatic and aromatic. Evidence for the different types of species involved in the production of higher hydrocarbons is obtained via isotopic labeling, continuous flow and transient experiments complemented by UV/Vis characterization of the catalyst and ab initio microkinetic modeling.