Four-faced Janus, the
god of transitions, now permits intercon
version of two
mirror ima
ges of a P-phenyl-phosphabarbaralane
via two ortho
gonal mechanisms at the same asymmetric center; a Walden-type in
version of a phosphonium salt and a Cope rearran
gement of its ca
ged cyclic hydrocarbon skeleton. More information can be found in the Full Paper by K. Nikitin and D. G. Gilheany et al. on
g/10.1002/chem.201604080" rel="references:https://doi.org/10.1002/chem.201604080">page 2332 ff.