Theoretical Investigation of the Te₄Br₂ Molecule in Ionic Liquids

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• 作者：Roman Elfgen ; Oldamur Holl&oacute ; czki ; Promit Ray ; Matthias F. Groh ; Michael Ruck and Barbara Kirchner
• 刊名：Zeitschrift für anorganische und allgemeine Chemie
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：643
• 期：1
• 页码：41-52
• 全文大小：2122K
• ISSN：1521-3749

文摘

Material synthesis in ionic liquids, at or near room temperature, is currently a subject of immense academic interest. In order to illuminate molecular-level details and the underlying chemistry, we carried out molecular simulations of a single Te₄Br₂ molecule dissolved in the ionic liquid 1-ethyl-3-methylimidazolium chloride, as well as in the ionic liquid mixed with aluminum chloride. Although the ethyl side chain is much too short to show detailed microheterogeneity, significant structuring with the small chloride anions is seen in case of the pure ionic liquid. In the case of the mixture, formation of larger anionic clusters is distinctly observed and analyzed. Due to the tendency of ionic liquids to dissociate, there is a pronounced shift to elongated Te–Br distances in both investigated solvents. However, only in the AlCl₃-containing liquid, we observe the reaction of the open chain-like Te₄Br₂ molecule to a closed square-like Te₄Br⁺ and AlCl₃Br^– ion. The molecular arrangement of the [Te₄]²⁺ unit shows negligible deviation from that in the experimental crystal structure.