Copper(II) Triflate-Catalyzed Aerobic Oxidative CH Functionalization of Glycine Derivatives with Olefins and Organoboranes
详细信息 查看全文
- 作者：Zhiyu Xie ; Jiong Jia ; Xigong Liu and Lei Liu
- 关键词：aerobic oxidation ; CH functionalization ; copper ; olefins ; organoborane.
- 刊名：Advanced Synthesis & Catalysis
- 出版年：2016
- 出版时间：March 17, 2016
- 年：2016
- 卷：358
- 期：6
- 页码：919-925
- 全文大小：472K
- ISSN：1615-4169
文摘
An economical, and practical copper(II) triflate-catalyzed aerobic oxidative CH functionalization of glycine derivatives with olefins and organoboranes has been established. The mild reaction has an excellent functional group tolerance, and exhibits a broad scope with respect to both glycine derivatives and the two types of nucleophilic components, allowing for the facile synthesis of diverse substituted quinolines and glycine derivatives bearing various patterns of functionalities in the -position.