[NMe₄][I₄Br₅]: A new Iodobromide from an Ionic Liquid with Halogen-Halogen Interactions

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• 作者：Lisa Mann ; Patrick Voß ; nacker ; Dr. Carsten M&uuml ; ller and Prof. Sebastian Riedel
• 刊名：Chemistry - A European Journal
• 出版年：2017
• 出版时间：January 5, 2017
• 年：2017
• 卷：23
• 期：2
• 页码：244-249
• 全文大小：2087K
• ISSN：1521-3765

文摘

Tetramethylammonium tetraiodopentabromide [NMe₄][I₄Br₅] was the first iodobromide to be synthesized and crystallized in an ionic liquid as well as in dichloromethane. The new iodobromides show different structure motives yet are unknown from other nonahalides and can be better described as [(I₂Br₃)⁻⋅2 IBr]. The additional IBr units are connected by halogen–halogen interactions on the central V-shaped [I₂Br₃]⁻. The characterization was performed by Raman spectroscopy and single crystal X-ray structure determination. Conductivity measurements, thermogravimetric analysis and quantum-chemical calculations completed the structural discussion.