ChemInform Abstract: Divergent Synthesis of Indole-Fused Polycycles via Rh(II)-Catalyzed Intramolecular [3 + 2] Cycloaddition and C—H Functionalization of Indolyltriazoles.
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- 作者：Yong-Sheng Zhang ; Xiang-Ying Tang and Min Shi
- 关键词：cycloaddition reactions ; C-C bond formation ; spirocyclic compounds (heterocyclic compounds) ; azepine derivatives ; catalysis ; phase-transfer catalysis
- 刊名：ChemInform
- 出版年：2016
- 出版时间：March, 2016
- 年：2016
- 卷：47
- 期：13
- 全文大小：33K
- ISSN：1522-2667
文摘
A novel and efficient rhodium catalyzed Intramolecular [3 + 2] cycloaddition and C—H functionalization of indolyltriazoles to give access to polycyclic pyrroloindoles and azepino[4,5-b]indoles is presented.