General, Simple, and Chemoselective Catalysts for the Isomerization of Allylic Alcohols: The Importance of the Halide Ligand
详细信息 查看全文
- 作者：Elis Erbing ; Dr. Ana Vá ; zquez-Romero ; Dr. Antonio Bermejo&ensp ; Gó ; mez ; Dr. Ana E. Platero-Prats ; Dr. Fabian Carson ; Prof. Xiaodong Zou ; Dr. Pä ; ivi Tolstoy and Prof. Belé ; n Martí ; n-Matute
- 刊名：Chemistry - A European Journal
- 出版年：2016
- 出版时间：October 24, 2016
- 年：2016
- 卷：22
- 期：44
- 页码：15659-15663
- 全文大小：664K
- ISSN：1521-3765
文摘
Remarkably simple IrIII catalysts enable the isomerization of primary and sec-allylic alcohols under very mild reaction conditions. X-ray absorption spectroscopy (XAS) and mass spectrometry (MS) studies indicate that the catalysts, with the general formula [Cp*IrIII], require a halide ligand for catalytic activity, but no additives or additional ligands are needed.