We describe a three-step one-pot metal-free domino procedure yielding a set of boscalid der
ivat
ives, parent compound being a highly important agrochemical agent. The first step of the process consists of the
Diels–Alder reaction between a substituted
2H-pyran-2-one and styrene der
ivat
ives, followed by the elimination of CO
2 and
aromatization (oxidation). The last step was found to be efficiently promoted by the application of
chloranil as the oxidant. Alternat
ively,
activated carbon Darco KB could also act as the
dehydrogenation catalyst necessitating a larger excess of the
styrene to act as the hydrogen acceptor.