Rhodium-Catalyzed Vinylic C-H Functionalization of Enol Carbamates with Maleimides
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- 作者：Satyasheel Sharma ; Sang Hoon Han ; Hyeim Jo ; Sangil Han ; Neeraj Kumar Mishra ; Miji Choi ; Taejoo Jeong ; Jihye Park and In Su Kim
- 刊名：European Journal of Organic Chemistry
- 出版年：2016
- 出版时间：July 2016
- 年：2016
- 卷：2016
- 期：21
- 页码：3611-3618
- 全文大小：1511K
- ISSN：1099-0690
文摘
The rhodium(III)-catalyzed direct C–H functionalization of enol carbamates with a range of maleimides is described. With the assistance of the carbamoyl directing group, this reaction provides biologically relevant succinimide compounds by proceeding through a C–Rh addition and subsequent protonation pathway.