文摘
The metal sulfide-carbon nanocomposite is a new class of anode material for sodium ion batteries, but its development is restricted by its relative poor rate ability and cyclic stability. Herein, we report the use of double-helix structure of carrageenan–metal hydrogels for the synthesis of 3D metal sulfide (MxSy) nanostructure/carbon aerogels (CAs) for high-performance sodium-ion storage. The method is unique, and can be used to make multiple MxSy/CAs (such as FeS/CA, Co9S8/CA, Ni3S4/CA, CuS/CA, ZnS/CA, and CdS/CA) with ultra-small nanoparticles and hierarchical porous structure by pyrolyzing the carrageenan–metal hydrogels. The as-prepared FeS/CA exhibits a high reversible capacity and excellent cycling stability (280 mA h−1 at 0.5 A g−1 over 200 cycles) and rate performance (222 mA h−1 at 5 A g−1) when used as the anode material for sodium-ion batteries. The work shows the value of biomass-derived metal sulfide–carbon heterostuctures in sodium-ion storage.