ChemInform Abstract: Controlled TfOH- or AuCl-Catalyzed Cycloisomerization and Tandem Hydrolytic Defluorination of 1,2-Allenyl Perfluoroalkyl Ketones.

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• 作者：Can Xue ; Xin Huang ; Shangze Wu ; Chunling Fu and Shengming Ma
• 刊名：ChemInform
• 出版年：2016
• 出版时间：September, 2016
• 年：2016
• 卷：47
• 期：38
• 全文大小：30K
• ISSN：1522-2667

文摘

An efficient cycloisomerization of allenyl perfluoroalkyl ketones under the catalysis of gold(I) chloride (for trisubstituted allenones) or triflic acid (for fully substituted allenones) is described.