Cover Picture: Mild and Low-Pressure fac-Ir(ppy)3-Mediated Radical Aminocarbonylation of Unactivated Alkyl Iodides through Visible-Light Photoredox Catalysis (Chem. Eur. J. 27/2016)

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• 作者：Dr. Shiao Y. Chow ; Marc Y. Stevens ; Linda Å ; kerbladh ; Sara Bergman and Prof. Dr. Luke R. Odell
• 刊名：Chemistry - A European Journal
• 出版年：2016
• 出版时间：June 27, 2016
• 年：2016
• 卷：22
• 期：27
• 页码：9033
• 全文大小：630K
• ISSN：1521-3765

文摘

Iridium stands at the center of a vortex of electrons that are transferred to and from the surrounding reaction components in this radical aminocarbonylation method. The combination of visible-light irradiation and low-pressure ex situ carbon monoxide generation makes this an attractive and operationally simple approach for preparing β-hydride-containing alkyl amides. Additional cover art acknowledgements: Bobo Skillinghaug and Johan Sjöstedt. More information can be found in the Full Paper by L. R. Odell et al. on page 9155 ff.