Effect of Nb doping on the structural, morphological, optical and electrical properties of RF magnetron sputtered Inb>2b>Ob>3b> nanostructured films

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• 作者：R. Reshmi Krishnan ; S. R. Chalana ; S. Suresh ; S. K. Sudheer ; C. Sudarsanakumar ; M. C. Santhosh Kumar and V. P. Mahadevan Pillai
• 刊名：physica status solidi (c)
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：14
• 期：1-2
• 全文大小：1246K
• ISSN：1610-1642a

文摘

Undoped and niobium (Nb) doped indium oxide (Inb>2b>Ob>3b>) thin films are prepared by radio frequency magnetron sputtering technique. The effect of Nb on the structural, morphological, optical and electrical properties of Inb>2b>Ob>3b>films are analyzed using techniques such as X-ray diffraction (XRD), micro-Raman spectroscopy, X-ray photoelectron spectroscopy, atomic force microscopy, field emission scanning electron microscopy (FESEM), energy dispersive X-ray spectroscopy, UV–visible spectroscopy, spectroscopic ellipsometry, photoluminescence spectroscopy and Hall effect measurements. XRD analysis reveals that the as-deposited undoped and Nb doped films are polycrystalline in nature with cubic bixbyite structure. Raman analysis supports the presence of cubic bixbyite structure of Inb>2b>Ob>3b>in the films. XPS analysis shows a decrease of oxygen deficiency due to Nb and the existence of Nb as Nb⁴⁺ in the Inb>2b>Ob>3b>lattice. The band gap energy of the films increases with increase in Nb concentration. PL spectra reveal intense UV and visible emissions in all the films. Optical constants of the films are determined using spectroscopic ellipsometry. The thickness of films estimated using FESEM and ellipsometry are in good agreement. The carrier concentration, mobility and nature of carriers are measured using Hall measurement technique in Van der Pauw configuration at room temperature.