Frontispiece: Manganese-Mediated C−H Alkylation of Unbiased Arenes Using Alkylboronic Acids

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• 作者：Dr. Susana Castro ; Juan J. Ferná ; ndez ; Prof. Dr. Francisco J. Fañ ; aná ; s ; Dr. Rubé ; n Vicente and Prof. Fé ; lix Rodrí ; guez
• 刊名：Chemistry - A European Journal
• 出版年：2016
• 出版时间：June 27, 2016
• 年：2016
• 卷：22
• 期：27
• 全文大小：2538K
• ISSN：1521-3765

文摘

Alkylation The alkyl chain of boronic acids is transferred to simple unbiased arenes at the “manganese station” to get interesting alkylarenes. More precisely, manganese(III) acetate promotes the formal C−H alkylation of arenes with boronic acids as alkylating agents through a process where radicals seem to be involved. The possibility of accessing linear n-alkyl arenes by this method is particularly remarkable because traditional direct arene alkylation procedures (Friedel–Crafts alkylation) do not allow the synthesis of this particular type of compounds. For more details see the Communication by F. J. Fañanás, R. Vicente, F. Rodríguez et al. on p://dx.doi.org/10.1002/chem.201601482" rel="references:http://dx.doi.org/10.1002/chem.201601482">page 9068 ff.