Inside Cover: Activation of Dihydrogen by Masked Doubly Bonded Aluminum Species (Angew. Chem. Int. Ed. 41/2016)
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- 作者：Dr. Koichi Nagata ; Takahiro Murosaki ; Prof. Dr. Tomohiro Agou ; Prof. Dr. Takahiro Sasamori ; Prof. Dr. Tsukasa Matsuo and Prof. Dr. Norihiro Tokitoh
- 刊名：Angewandte Chemie International Edition
- 出版年：2016
- 出版时间：October 4, 2016
- 年：2016
- 卷：55
- 期：41
- 页码：12546
- 全文大小：1938K
- ISSN：1521-3773
文摘
Aluminum can activate dihydrogen! Al=Al doubly bonded species, generated by retro Diels–Alder reaction of bicyclic organoaluminum compounds bearing bulky aryl substituents, react with dihydrogen to afford the dimers of aluminum dihydride. In their Communication on page 12877 ff, N. Tokitoh and co-workers show that this hydrogen activation reaction proceeds under atmospheric pressure and at room temperature.