Back Cover: Asymmetric Cation-Binding Catalysis (ChemCatChem 3/2017)

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• 作者：Dr. Maria Teresa Oliveira and Prof. Ji-Woong Lee
• 刊名：ChemCatChem
• 出版年：2017
• 出版时间：February 6, 2017
• 年：2017
• 卷：9
• 期：3
• 页码：522
• 全文大小：712K
• ISSN：1867-3899

文摘

The Cover llustrates a BINOL-based catalyst activating fluoride atoms (yellow) by chelating their counter-cation (purple), with a fluorite stone in the background.In their Concept M. T. Oliveira et al. explain how alkaline metal salts can be employed in asymmetric catalysis. Recent examples on asymmetric cation-binding catalysis show high turnover numbers and excellent enantioselectivities for different types of reactions, owing to ion-pairing interactions. This summary will certainly inspire investigation of new activation modes and open up a plethora of possibilities in asymmetric catalysis. More information can be found in the Concept by M. T. Oliveira et al. on page 377 in Issue 3, 2017 (DOI: 10.1002/cctc.201601441).