ChemInform Abstract: Palladium(II)-Catalyzed Annulation of Alkynes with 2-(Cyanomethyl)phenylboronates Leading to 3,4-Disubstituted 2-Naphthalenamines.

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• 作者：Hirokazu Tsukamoto ; Taishi Ikeda and Takayuki Doi
• 刊名：ChemInform
• 出版年：2016
• 出版时间：June, 2016
• 年：2016
• 卷：47
• 期：28
• 全文大小：27K
• ISSN：1522-2667

文摘

This reaction proceeds through transmetalation of the palladium(II) complex with boronates and alkyne insertion followed by nucleophilic addition of the generated alkenylpalladium(II) species to the cyano group.