Front Cover: Implications of Guanidine Substitution on Copper Complexes as Entatic-State Models (Eur. J. Inorg. Chem. 29/2016)
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- 作者：Alexander Hoffmann ; Julia Stanek ; Benjamin Dicke ; Laurens Peters ; Benjamin Grimm-Lebsanft ; Alina Wetzel ; Anton Jesser ; Matthias Bauer ; Manuel Gnida ; Wolfram Meyer-Klaucke ; Michael Rü ; bhausen and Sonja Herres-Pawlis
- 刊名：European Journal of Inorganic Chemistry
- 出版年：2016
- 出版时间：October 2016
- 年：2016
- 卷：2016
- 期：29
- 页码：4721
- 全文大小：1359K
- ISSN：1099-0682c
文摘
The cover picture shows a guanidine–quinoline–copper complex as a new entatic-state model. Small changes in the ligand strongly affect the molecular structure, which demonstrates the subtle balance of steric and electronic effects at a metal center. The unique combination of solid-state and solution structural investigations by classical single-crystal X-ray diffraction and X-ray absorption spectroscopy together with density functional theory reveals deep insights into this entatic-state model. Details are discussed in the article by S. Herres-Pawlis et al. on p. 4731 ff. For more on the story behind the cover research, see the Cover Profile.