A Facile and Efficient Method to Fabricate Highly Selective Nanocarbon Catalysts for Oxidative Dehydrogenation

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• 作者：Yajie Zhang ; Jia Wang ; Junfeng Rong ; Dr. Jiangyong Diao ; Jiayun Zhang ; Chunfeng Shi ; Prof. Hongyang Liu and Prof. Dangsheng Su
• 刊名：ChemSusChem
• 出版年：2017
• 出版时间：January 20, 2017
• 年：2017
• 卷：10
• 期：2
• 页码：353-358
• 全文大小：1212K
• ISSN：1864-564X

文摘

Carbon nanotubes (CNTs) were used in oxidative dehydrogenation (ODH) reactions. Quinone groups on the CNT surface were identified as active sites for the dehydrogenation pathway. Liquid-phase oxidation with HNO₃ is one way to generate various oxygen functionalities on the CNT surface but it produces a large amount of acid waste, limiting its industrial application. Here, a facile and efficient oxidative method to prepare highly selective CNT catalysts for ODH of n-butane is reported. Magnesium nitrate salts as precursors were used to produce defect-rich CNTs through solid-phase oxidation. Skeleton defects induced on the CNT surface resulted in the selective formation of quinone groups active for the selective dehydrogenation. The as-prepared catalyst exhibited a considerable selectivity (58 %) to C₄ olefins, which is superior to that of CNTs oxidized with liquid HNO₃. Through the introduction of MgO nanoparticles on the CNT surface, the desorption of alkenes can be accelerated dramatically, thus enhancing the selectivity. This study provides an attractive way to develop new nanocarbon catalysts.