Manganese(I)-Catalyzed Substitutive C−H Allylation

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• 作者：Weiping Liu ; Sven C. Richter ; Yujiao Zhang and Prof. Dr. Lutz Ackermann
• 刊名：Angewandte Chemie
• 出版年：2016
• 出版时间：June 27, 2016
• 年：2016
• 卷：128
• 期：27
• 页码：7878-7881
• 全文大小：873K
• ISSN：1521-3757

文摘

The first manganese(I)-catalyzed C−H allylations with ample scope were achieved by carboxylate assistance. The highly selective C−H/C−O functionalizations proved viable with densely substituted allyl carbonates, and the organometallic C−H allylation strategy set the stage for expedient late-stage diversification with excellent levels of positional selectivity.