Selective B(4)−H Activation of an o-Carboranylthioamide Based on a Palladium Precursor
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- 作者：Yin-Ping Wang ; Long Zhang ; Dr. Yue-Jian Lin ; Prof. Dr. Zhen-Hua Li and Prof. Dr. Guo-Xin Jin
- 刊名：Chemistry - A European Journal
- 出版年：2017
- 出版时间：February 3, 2017
- 年：2017
- 卷：23
- 期：8
- 页码：1814-1819
- 全文大小：808K
- ISSN：1521-3765
文摘
Palladium(II)-induced selective B(4)−H activation of an o-carboranylthioamide has been developed. A tetranuclear palladium(II) complex has been obtained in high yield with excellent regioselectivity. DFT calculations have confirmed that the B(4)-borometalate is lower in energy than the corresponding B(3)-borometalate. The product proved to be a good precursor for target mononuclear or trinuclear B(4)−H activated complexes.