Fe3O4-Decorated Co9S8 Nanoparticles In Situ Grown on Reduced Graphene Oxide: A New and Efficient Electrocatalyst for Oxygen Evolution Reaction

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• 作者：Jing Yang ; Guoxing Zhu ; Yuanjun Liu ; Jiexiang Xia ; Zhenyuan Ji ; Xiaoping Shen and Shikui Wu
• 刊名：Advanced Functional Materials
• 出版年：2016
• 出版时间：July 12, 2016
• 年：2016
• 卷：26
• 期：26
• 页码：4712-4721
• 全文大小：2448K
• ISSN：1616-3028

文摘

Cobalt sulfide materials have attracted enormous interest as low-cost alternatives to noble-metal catalysts capable of catalyzing both oxygen reduction and oxygen evolution reactions. Although recent advances have been achieved in the development of various cobalt sulfide composites to expedite their oxygen reduction reaction properties, to improve their poor oxygen evolution reaction (OER) activity is still challenging, which significantly limits their utilization. Here, the synthesis of Fe₃O₄-decorated Co₉S₈ nanoparticles in situ grown on a reduced graphene oxide surface (Fe₃O₄@Co₉S₈/rGO) and the use of it as a remarkably active and stable OER catalyst are first reported. Loading of Fe₃O₄ on cobalt sulfide induces the formation of pure phase Co₉S₈ and highly improves the catalytic activity for OER. The composite exhibits superior OER performance with a small overpotential of 0.34 V at the current density of 10 mA cm⁻² and high stability. It is believed that the electron transfer trend from Fe species to Co₉S₈ promotes the breaking of the Co–O bond in the stable configuration (Co–O–O superoxo group), attributing to the excellent catalytic activity. This development offers a new and effective cobalt sulfide-based oxygen evolution electrocatalysts to replace the expensive commercial catalysts such as RuO₂ or IrO₂.