Synthesis of Mesoporous Transition-Metal Phosphates by Polymeric Micelle Assembly

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• 作者：Dr. Bishnu Prasad Bastakoti ; Dr. Yunqi Li ; Dr. Sudhina Guragain ; Dr. Malay Pramanik ; Prof. Saad M. Alshehri ; Dr. Tansir Ahamad ; Dr. Zongwen Liu and Prof. Yusuke Yamauchi
• 刊名：Chemistry - A European Journal
• 出版年：2016
• 出版时间：May 23, 2016
• 年：2016
• 卷：22
• 期：22
• 页码：7463-7467
• 全文大小：2710K
• ISSN：1521-3765

文摘

Mesoporous iron phosphate (FePO₄) was synthesized through assembly of polymeric micelles made of asymmetric triblock co-polymer (polystyrene-b-poly-2-vinylpyridine-b-ethylene oxide; PS-PVP-PEO). The phosphoric acid solution stimulates the formation of micelles with core–shell-corona architecture. The negatively charged PO₄³⁻ ions dissolved in the solution strongly interact with the positively charged PVP⁺ units through an electrostatic attraction. Also, the presence of PO₄³⁻ ions realizes a bridge between the micelle surface and the metal ions. The removal of polymeric template forms the robust framework of iron phosphate with 30 nm pore diameter and 15 nm wall thickness. Our method is applicable to other mesoporous metal phosphates by changing metal sources. The obtained materials were fully characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), N₂ adsorption–desorption, Raman spectroscope, and other techniques.