Back Cover: Two Independent Orthogonal Stereomutations at a Single Asymmetric Center: A Narcissistic Couple (Chem. Eur. J. 10/2017)
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- 作者：Malachi W. Gillick-Healy ; Dr. Elizabeth V. Jennings ; Dr. Helge Mü ; ller-Bunz ; Dr. Yannick Ortin ; Dr. Kirill Nikitin and Prof. Declan G. Gilheany
- 刊名：Chemistry - A European Journal
- 出版年：2017
- 出版时间：February 16, 2017
- 年：2017
- 卷：23
- 期：10
- 页码：2477
- 全文大小：1518K
- ISSN：1521-3765
文摘
Four-faced Janus, the god of transitions, now permits interconversion of two mirror images of a P-phenyl-phosphabarbaralane via two orthogonal mechanisms at the same asymmetric center; a Walden-type inversion of a phosphonium salt and a Cope rearrangement of its caged cyclic hydrocarbon skeleton. More information can be found in the Full Paper by K. Nikitin and D. G. Gilheany et al. on doi.org/10.1002/chem.201604080" rel="references:https://doi.org/10.1002/chem.201604080">page 2332 ff.